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Blog
Four boron frits with vastly different melting:
Knowing about this could debubble your clear glaze.
Industry, late-melting glazes are a must for fast fire because there is no time for glazes to debubble. The later they melt (while still melting well at the target temperature), the more LOI gases of decomposition (generated by the body, glaze materials, glaze & body additives) can be expelled first. What about potters? These melt flow tests are of specific interest to anyone making clear glazes using frit 3134. They compare four common Ferro products fired to 1750F: Frit 3249 (29% B2O3), frit 3124 (14% B2O3), frit 3195 (23% B2O3) and frit 3134 (23% B2O3). Surprisingly, the one having the most B2O3 starts melting the latest (more than 200F after 3134), this is because of the amount of MgO in the formula. So, if your transparent glaze contains any MgO (G2926S, for example, contains 0.15 molar), the more that can be supplied using this (instead of 3134), the later the glaze will melt. Likewise, frit 3124 is a better choice than 3134 in cases where the percentage of clay can be reduced (since it supplies much more Al2O3). Glazes containing high percentages of feldspar are least likely to benefit because the main alternative source of KNaO is frit 3110, and it melts even sooner than 3134 (an exception is cases where the glaze also has high MgO and B2O3).
This is a cone 6 transparent fritted glaze (converted from a Gerstley Borate one). Its B2O3 content is high, sourced by Ferro Frit 3134. Bubbles like this plague many potters, many just keep trying new glazes until one works, or give up on never finding one.
The first obvious problem is the frit, it starts melting at 1350°F, while plenty of gases are still being generated. Such a bubble-trapper is a non-starter in an industrial continuous fast-fire kiln. They need late melters. But potters have flexible firing, so what could be done? The firing could be slowed down, leading up to 1350. It could be held at top temp, then either slow cooled or a drop-and-hold. And the recipe? Notice the big bubbles; they started as little ones that merged. Given enough time, big ones break at the surface, but only under the right conditions: Low enough melt viscosity and surface tension. That's not happening. Strangely, old recipes sourcing high boron from Gerstley Borate had surprisingly few problems with bubbles! Why? GB was its own fining agent. And its boron entered the melt much later than this frit. Plus, the melt developed unevenly, creating localized channels and variable viscosity zones for easier bubble escape. The larger bubbles could better move laterally by combinations of surface tension, layer thickness and temperature gradients, and downward movement that created shear. A frit is missing all of that.
Let's assume this glaze melt has high surface tension. It pulls liquid inward around each bubble, stabilizing them round and making rupture more difficult. But, if surface tension drops, even slightly, bubbles deform more easily and adjacent ones merge. What could help? Industrial technicians have found that surprisingly small changes can really help with bubble release.
-A small SiO2 or Al2O3 addition can delay surface sealing or change viscosity timing.
-Sourcing the CaO from wollastonite can help bubble coalescence and reduce melt surface tension.
-Zinc oxide often changes surface behavior more than expected. As little as 2% can alter the viscosity curve, surface tension and melt interface properties, weakening bubble walls and improving near-surface rupture.
-Although MgO stiffens the melt somewhat, it also changes bubble wall elasticity; even small additions can help bubbles merge better.
As usual with solutions found here, methodical testing is needed to find the best answer.
Potters often encounter the problem shown here. These pieces are fired at cone 6. They are decorated with underglazes made from a mix of porcelain powders and stains. The transparent glaze works over certain colors (e.g. the light blue), but over others, it is full of microbubbles and pinholes. The potter has not had success finding a transparent overglaze that works consistently. As can be seen here, stain types used in underglazes behave differently; they are not just inert powders. Also, stain manufacturers do not mix stains with porcelain to making underglazes.
So, although closer control of the transparent glaze thickness or a more fluid melt glaze recipe might help, the real solution lies with the underglaze recipes used here. An ideal bisque-stage underglaze is sinter-bonded but not sealed, accepting glaze water. An ideal fired underglaze also has controlled maturity: enough glass development to bond well to the body and promote glaze acceptance, but not so much that edge-bleeding and opacity loss occur. This state of 'partial vitrification' is also more likely to match body thermal expansion. The cost savings and the potential to fine-tune each color to your exact needs can be powerful motivations to use DIY underglazes.
As potters, we learned that no one is affected by supply chain problems more than prepared glaze manufacturers; they have complex recipes that require complex supply chains. It wasn't just availability; product consistency was also affected. It is again time to think about DIY, to start learning how to weigh out the ingredients to make at least some of your own. Arm yourself with good base recipes that fit your clay bodies (without crazing or shivering). Add stains, opacifiers and variegators to the bases to make anything you want. Admittedly, ingredients in your recipes can also become unavailable! But DIY as about options. When you "understand" glaze ingredients and what each contributes to the recipe and oxide chemistry, you are equipped to go well beyond weathering material supply issues. You will improve recipes, not just adjust them, to accommodate alternative materials. It is not rocket science; it is just work accompanied by organized record-keeping and good labelling.
This is a cone 6 oxidation transparent glaze having enough flux (from a boron frit) to make it melt very well, that is why it is running and pooling. Iron oxide has been added (around 5%), producing this transparent amber effect. Darker coloration occurs where the glaze has run thicker (because it absorbs more light). This simple mechanism enables the glaze to automatically highlight contours, emboss and textures on the underlying surface. This mechanism works with any color in almost any transparent base glaze, as long as bubble clouding and crystallization do not occur. Entire lines of commercial glazes (e.g. AMACO Celadons) are based on this mechanism and potters prize it (industry doesn't like it because it is difficult to achieve consistency).
This glaze relies on high levels of K2O and Na2O to produce the brilliant gloss, however the side effect of that is crazing. These are sourced by feldspars, nepheline syenite and are high in certain frits. To achieve this effect, recipes must rely on other fluxes like boron, lithium or zinc.
The more complex your supplier's supply chain, the more likely they won't be able to deliver. And that prices will rise even further. How can you adapt to disruptions, even turn them into a benefit? Historically, pottery has been a shining star of resilience and independence because the materials were in the ground nearby. You cannot likely head out to the nearest hill with your wheelbarrow to get clay, but you can do something even better.
Rather than viewing these containers as full of specific brand-name clays, minerals and man-made powders, it is better to view them as full of materials that supply the physical properties and chemistries needed to make bodies, glazes, engobes, slips, etc. By characterizing your glazes and bodies, using an effective record-keeping system, you can not only adjust recipes to adapt to changing supplies, but even improve them in the process (adjusting glaze thermal expansion, temperature, surface, color, etc). Or, use materials native to your area. It is not rocket science; it is just work and gradual learning accompanied by organized record-keeping, good labelling and interpretation skills.
Peggy-potter makes the hand-crafted mugs. Carla-coffee-drinker, needs a mug. This apparent perfect alignment goes off the rails when Carla compares Peggy's $50 price with premium imported mugs costing $5 (shown here). Especially when the imports emulate Peggy's techniques flawlessly while offering better durability and strength!
Peggy has to choose between hyping "kiln drops" on social or cutting costs. DIY techniques and supplies are a first option. Also mold-making and slip casting, even mixing her own casting slips. Mixing her own glazes, underglazes and engobes is the next step. Or learning to use less expensive bodies (e.g. with engobes).
Going DIY is not a big equipment investment. A plaster table, scale, mixing and batching table and a propeller mixer are the most important. And keeping good records (e.g. an account at insight-live.com). Following manufacturers on Instagram to see their glazing and forming techniques can help. Build throwing and drying skills by making hundreds of the same item. Consider: What you do affects other potters, prices cannot keep rising, or there will be no market.
Strips of the same glaze recipe, each containing different percentages of zirconopacifier, have been applied across both a dark-burning body and a white engobe. While it is difficult to measure the absolute degree of opacity from a photo like this, the side-by-side comparison makes differences easy to see. Tests like this demonstrate that simple visual comparisons can often be as useful as instrument measurements when evaluating glaze opacity. Colorimeters measure Lab* color values, not opacity directly. This test is really about visual hiding power, which instruments don't always capture well.
In this case the technician may be trying to determine how to achieve the required whiteness at minimum cost. Both the engobe and glaze contain zircon. The whiter the engobe the less opacifier is required in the glaze over it. Zircon is an expensive material, and reducing the total needed by even by 1% can make a significant difference in production cost.
The same test method can also be used to compare different brands of zircon opacifier in the same recipe.
A subtle aspect can be noted by coverage on the dark body: Opacity differences there become visible, whereas on the white engobe, differences almost disappear. Where an engobe is not to be used, an effective tweak is to add a thin black line under the glaze, then the lowest zircon level that hides the line becomes obvious.
Are your records in a messy binder? Binders don't have "Search" buttons. Side-by-sides. And many DIYers would generate a binder full in a year. But how does one even start to organize?
Start by moving your recipes to an account at insight-live.com, assigning each a code number. Then, in your studio/lab, label every fired sample, bucket, jar, glaze test, bag with the corresponding code number. Upload pictures for each recipe. Enter your firing schedules. Research the solutions to issues you are facing with glazes at the Digitalfire Reference Library (ask us questions using the contact form on each of the thousands of pages there). Then start planning improvements and tests. Choose a recipe you need to improve/evolve, duplicate it, increment the code number, make changes, enter explanatory notes. With this preparation you will hit the ground running back at work.
The mug on the left, #1, is a commercial brushing glaze. It is opaque enough to cover this red-burning clay body. It shows the desired effect. That depends on the fact that opaque glazes stretch thinner on the sharp edges of incised designs. If they have enough melt mobility and are applied right, the effect is amplified. This potter is attempting to mix her own DIY equivalent as a dipping glaze, adding 4% tin oxide to a transparent base glaze in #2 and zircon (a higher percentage) in #3. As you can see, the effect is not working as well, and there are several reasons:
#2 is whiter because it uses tin oxide as the opacifier (vs. zircon, likely used in #1). #2 and #3 have less melt fluidity; the base is likely G2926B. #1 was applied by brush, the others using a dipping glaze. Matching the original involves a combination of things: A base having more flux (especially B2O3) is needed (e.g. G3806C). Careful control of application thickness. The right percentage of opacifier. And, it may be necessary to mix the DIY version as a brushing glaze, that method of application might be needed to get the careful control of thickness and thickness variation needed.