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Chemistry plus physics.
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I have never understood the chemistry part of clay and glazes, so what
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This site is very informative. If the average layperson were to read this site, they would be blown away, and in my case, inspired to learn more. I like to give credit where credit is due, and this site rocks.
I just read the Magic of Fire cover to cover...I feel that a gift from heaven fell into my lap at just the right time. Two months ago I couldn't have appreciated your advice...The reality of tests too numerous to comprehend had just hit me. Your advice to establish a base glaze that is shown by testing to be well fitted,and to create variations from there seems to sensible but I didn't see it for myself. I was on my way to a workshop about commercial glazes...Armed with a new attitude, I now wonder if I need these samples?
Am finding your website a treasure trove of extremely thoughtful writings for the aspiring more-technical studio potter. Thanks for putting it out there.
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I have been in this ceramic line with 15 years experience covering the idustires right from porcelain insulators,vitrified tiles etc., With the help of chemistry graduation I started my career in the cermaic industry. This website is very much helpful in fine tuning and upgrading my experience with enhanced knowledge of ceramics.
I normally do not comment on articles I find, but this is amazing. Thank you so much for providing this information! I am a ceramics student in my BFA year, and this is the most comprehensive and helpful information I have found on creating a porcelain casting slip.
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I just want to thank you for this most interesting and informative article. I just did a general search for the compatibility of a stoneware glaze on porcelain, and your page came up! Wow! what a mine of information and just what I needed as I was also looking for a slip recipe for my students.
Cannot imagine what I would do without my Insight-live.
I just wanted to say, thank you! I’m relatively new to pottery, taking a mostly self-taught approach and I’m at the stage where glazing is in my mind. I don’t want to be (and can’t see myself ever) buying glazes from commercial suppliers. I want to learn my craft with glaze as much as I do with my clay preparation and pottery making. I’ve seen “the dragon” and been uninspired by so much of what I find online and to be honest, in many glaze books. It seems more popular to try and present a mass of glaze possibilities than to offer a learning experience beyond being told a glaze needs a melter, a refractory and a glass-maker. Enough to offer a very basic understanding, but nothing upon which to build the understanding that will allow some degree of mastery (or at least influence) of your glaze making.
I am so pleased to have found digitalfire.com. You’ve shown me exactly how to approach and understand glazing, giving me the foundation for approach I sought. I was thinking of base glazes and what you’ve shown me about working on from those is fantastic and exactly what I was looking for. To have a reliable base glaze to modify and develop to meet different needs; to understand how to shift a melting point or adjust the surface gloss; to come to know how the mechanisms in a glaze and understanding them gives me the route to creating glazes that realize my intentions - wow!
I can’t thank you enough. Rather than having to form a dumb reliance on a book of recipe cards and a bunch of website bookmarks (which I wasn’t wanting to go for) you’ve given me the foundation for a lifelong development and understanding of the glazes I will make, that will become “my” glazes. You have really opened my mind to the whole subject and it doesn’t seem to be a problem that I’m no scientist or chemist. You’ve shared your knowledge in a way that is completely approachable and remarkably easy to understand for someone without any kind of science/chemistry background.
With a major in ceramics i have been working in the glaze lab of a big sanitary ware production company for about 3 years now. I want to tell you how much i appreciate the work that you do and the knowledge that you share, through out the 7 years that i have been studying and working in the Ceramics field. You have been the most important source of knowledge for me no one has ever taught me as much as you did through digitalfire. I truly love ceramics its quite a beautiful field to work in and i love and excel at what i do and big part of that is because of the guidance that you provide. And that really means alot to me to see a research or a test work out as i planned.
First i'd love to thank you for all the info you provide on digitalfire. it is an absolutely amazing resource and the way that you explain glaze chemistry/reactions has really helped expand my practice...I crave understanding and wisdom.
Your site is the most useful of them all for material info. and more. Thank you.
Blog
Fine-tuning the thixotropy of a glaze or engobe
For dipping, this is so much better!
Watch this 30-second video to see. Gelled (thixotropic) slurries for dipping are so much better to work with; you'll never go back once you have mastered this DIY technique. While some glazes and engobes gel naturally, especially those with high clay content, these almost always work best when the water content is within a certain range, so fine-tuning like this is still needed. Although not shown here, if over-gelling happens, a drip or two of deflocculant (e.g. Darvan) brings back the fluidity, this is more likely to happen with engobes since they need more gel (for dipping and even more for painting). A side benefit of this: No settling in the bucket.
Quick fix to make these spareless molds more usable
These legacy slip casting molds from Medalta Potteries (made from 80 year old masters). They are difficult and time-consuming to use and produce less than optimal results because they have no top section (this no spare) and require constant filling during cast time. Demolding requires cutting the lip flat (top right). But a lot of time trimming and sponging is needed to round it again, but making the lip even and symmetric is difficult to say the least.
I found a way to make these molds easier to use and better: A 3D printed spare/pouring spout that also defines a rounded rim. It can be glued to the top of the mold with slip. Of course, the PLA print is not absorbent, but this still works because the mold top edge is able to dewater the slip even inside the contoured top it forms. The print also acts as a cutting guide to cleanly cut anway any clay inside the spout section, leaving a clean line inside the lip. And the shrinkage of the clay pulls the pitcher lip away from the print.
The Heartbeat of the Kiln: The Indispensable Plant Technician
This page is dedicated to the skill and intuition of the Plant Technicians who kept the ceramic industry in North America thriving before the 1980s. Before we started clicking buttons to outsource things. They weren’t “role fillers” supplied by HR, they were “believers”. They understood everything in the plant; the equipment, processes, procedures, materials, recipes, kilns and firing. Managers set the pace, but the technicians made the pace possible. It was a time of local knowledge and company loyalty. They weren't temporary consultants or voices on a helpline; they owned and solved the problems. They were also mentors who passed their knowledge down.
These binders hold 40 years of recipes and techniques, kept by Albert E. Holthaus at Modern Art Products and Tierra Royal Potteries. Men like him were a legacy; they were the true "operating system" of a golden age of independence. They ensured the wheels kept turning, the fires kept burning and the quality kept enduring.
This batch-to-formula calculation was done by Albert E. Holthaus at Modern Art Products Company in Kansas City, MO (during the 1960s). Doing this not only seems quaint today, but suppliers put up roadblocks to doing it.
Notice that he took the manufacturer-supplied percentage analysis for each material (bottom) and calculated the unity formula for use in his batch to formula calculation (top). The recipe material weight amounts are missing in the latter; this appears to be his effort to create a documentation page of the recipe on the oxide formula level (this is what mattered to him). It was a time when frit formulas were published by their manufacturers. He also calculated the glaze's chemistry as a percentage analysis, likely to lay a basis to assess it against stated requirements from stain suppliers (certain stains only work when the host glaze chemistry meets a certain profile).
Doing this now is so much simpler. But almost no one actually does! The closest most technicians get to oxide formulas is choosing a frit from a list of ones for which the chemistry given by the manufacturer is only approximate.
This reduction stoneware glaze is producing white streaks on some pieces (left center). The body is a coarse iron stoneware. A magnification is needed to better explain this.
It is 2025, many smartphones now have dedicated macro lenses and can be held as close as a 1 centimeter. They automatically sense placement and switch to using the macro lens. Of course, the phone must be held rock steady and good lighting is essential. If you are a doubter of what they can produce, look at the two magnifications on the right. On the top one, the white streak is clearly visible, floating in a sea of phase-separated glass patterned by earlier-escaping bubbles. The extreme magnification on the bottom right appears to implicate tiny crystals growing in an area where late bubbles have escaped, changing the pattern of phase separation. This doesn’t yet explain the cause, but it is valuable information courtesy of a macro lens.
There’s DIY magic in the ground beneath your feet!
Place: Vernon, Alabama.
Story: Potter's friend sends a picture of an outcrop of white clay in the ditch near his driveway.
Result: A DIY claybody is born.
This planet is full of accessible clay deposits. Many can be used as-is for stoneware, earthenware and even porcelain. Characterizing this clay is the first step. How plastic is it? What does it look like when fired at different temperatures? Does it contain impurities that need to be sieved out? Does it dry without cracking? Does it work with glazes? Etc.
A journey of clay discovery to a finished piece is one of the most rewarding experiences you can have as a potter. And be more self-reliant. You don’t need special gear, just curiosity, eyes that notice, a few simple tools, and a willingness to experiment and learn to characterize clays. And one more thing: An organized way to keep records of your testing. Think of an insight-live account as a commitment to building experience; it is your memory of everything that worked. And didn't.
Or, more correctly, is this one a clay? The way I found out was to test it myself. That's what I did.
The giveaway of its marine origin is the tiny shells found on the sieve. The Cretaceous Sea once connected the Arctic Ocean with the Gulf of Mexico, covering the great plains of North America. Sedimentation left this deposit of Diatomaceous earth in central Alberta, Canada. This sample contains enough clay that I was able to slurry it up, dewater it on a plaster bat and then prepare SHAB test bars to try it at five temperatures. At cone 10 (bottom right) the porosity is 62%! And the LOI is 32% (others can go as high at 50%). Why? Raw diatomaceous earth contains physically bound interlayer water, it leaves by ~100–300 °C. It also contains structural hydroxyl water (in clay minerals or hydrated silica phases). This “chemical water” burns off between ~400–700 °C. And, organic matter from ancient algae, plants, or soil contamination also burns out between ~300–800 °C (as CO₂ and other gases). Finally, the carbonates (e.g. shells shown here) decompose around 700–900 °C, releasing CO₂. That alone can cause a big weight loss.
Note the test bars under it. Where this bar was sitting there is glassy deposit. What is that? Diatomaceous earth is mostly amorphous silica, but it almost always contains alkali and alkaline-earth impurities and sometimes boron. The latter can literally drain out, as a liquid. However here, the alkalis have volatilized (vaporized) or form alkali-rich fumes. These landed on nearby surfaces to react with the other test bars to form a thin alkali-silicate glass layer (similar to what happens in soda firing).
This is G3948A (similar to the popular Amaco Ancient Copper product). To get this stunning result, it needs to be applied thickly. Therefore, it runs a lot. But the catcher glaze around the bottom of these mugs has stopped the flow. The catcher is a glossy black, G3914A (but Amaco Obsidian would also likely work). I have learned to put it on with the right height (about 2cm) and right thickness, and then apply wax emulsion to prevent the iron red glaze from sticking during dipping. The inside glaze, G2926B, is one I have tested and developed to fit Plainsmanclay bodies as a liner.
Converting a glossy transparent glaze to a calcia matte
A ten-minute video to give glaze nerds goose bumps!
Watch the G1214Z video to see me convert the G1214Mcone 6 clear base into G1214Z cone 6 calcia matte using simple glaze chemistry and recipe logic. This first appeared in the Digitalfiredesktop Insight instruction manual 30 years ago. It is an understatement to say that this process is interesting if you want to know more about glazes, their chemistry and recipe logic. Watch this video and see me adjust the recipe of my high-calcium transparent cone 6 glaze to convert it into a calcia matte. In an Insight-live.com account, the process is easy enough for anyone. We'll cut the Si:Al ratio, increase the CaO, maintain the thermal expansion for glaze fit and make the recipe shrinkage-adjustable using a mix of calcinedkaolin and raw kaolin. We will even compare it with the High Calcium Semimatte from Mastering Glazes.
Ceramic glazes, like this GA6-B, are actually just glass. But they are not like bottle glass. The latter is formulated to work well in forming machines (harden quickly), melt and stiffen quickly, have low melt viscosity and resist milkiness and crystallization on solidification. The chemistries to accomplish this have adequate resistance to leaching and adequate durability for a few uses. A stoneware glaze melt needs to be much more viscous (to stay put on vertical surfaces). And, it must have a lower thermal expansion (to match common clay bodies). And, it must resist crystallization much more (since it cools slowly). Fortunately, meeting these needs brings along big benefits: Greater durability, hardness and resistance to leaching. Stoneware glazes and bottle glass share a common trait: They have about the same amount of SiO2. But the similarity ends there, stoneware glazes have:
-High Al2O3. Three to five times more! It is the key oxide for durable glass. And it stiffens the melt (that disqualifies high levels from bottle glass).
-The same fluxes (CaO, MgO, K2O, Na2O). But they distribute very differently (half the CaO, half to one third the KNaO, much more MgO). Other fluxes like SrO, Li2O are also common.
-Low KNaO (which they call R2O). In glazes, it produces crazing, 5% is a typical maximum. But bottle glass can have double or triple that (the high thermal expansion is not an issue, and its cheap source materials supply lots of melting power).
-B2O3 melter. It is expensive but can be justified because the glaze is just a thin layer. Glazes at the low end of the stoneware range have 5% or more boron.
Far right: A glass bottle. Left: Small test bottles made from dark and light burning stonewares. Third: A production ceramic bottle. Notice how much the dark body darkens the GA6-B glaze.