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Blog

LOI-gassing and expensive Spodumene

Blisters that enhance variegation, then heal

This pitcher was made by Elora Pottery. Like everyone using glazes that require lithium (from Spodumene or Lithium Carbonate), they are facing the unbelievable price increases these materials are seeing. Staci actually calculated the weight applied to each piece, determining the $$ dip cost! Notice her costs on the photo. During efforts to reduce the spodumene content, I noticed the expensive carbonate colorants and asked if these were causing blisters in the glaze (because of gasing associated with their LOI). When I saw this picture, it became clear that they are. But in a good way. Part of the variegation we are seeing is doubtless the mechanical disturbance they cause in the fluid-melt phase-separated glass. But the melt fluidity of the glaze appears to be sufficient to heal them and smooth out the glass during cooling.

What did we do about the spodumene? We calculated to use lithium carbonate to supply the Li2O instead - it took one fifth as much.

Context: Lithium Carbonate, Spodumene, How to make Spodumene.., Here is why Petalite.., Lithium and Spodumene prices.., Variegation

Thursday 13th August 2026

How to make Spodumene using Lithium Carbonate

Spodumene is super expensive; one dunk in a dipping glaze can now cost dollars. But lithium carbonate is even more so. However, both are used as a source of Li2O. The latter is 6+ times more concentrated. And spodumene is more troublesome in glazes (issues with settling, dusting, slurry properties, consistency). And it can be hard to get. So using the pure lithium material might be a better choice for you.

This side-by-side calculation seems to indicate that 15 Lithium Carbonate, 55 Kaolin and 30 Silica can substitute for 100 parts by weight of Laguna Spodumene Substitute. However, that is not quite correct. Note that my substitute recipe calculates to an LOI of 16.3. If I assume the Laguna material has no LOI (for convenience, it actually has 0.2%), that means each of the amounts need to be divided by (100-16.3)/100=0.84. Thus, to substitute for 100 parts of spodumene, you need ~120 of this mix (18 lithium carbonate, 66 kaolin and 36 silica).

Context: LOI-gassing and expensive Spodumene.., Li2O from Spodumene instead..

Thursday 13th August 2026

Spin-glazing bisque-fired plates in a factory

These plates are made at the HomeVSS factory in China. The plate is placed on a soft rubber-surfaced spinning wheelhead that is rotating fast enough that a ladle full of glaze poured into the center is expelled within a second and dries within four seconds. At the two-second mark, a sponge is used to catch drips and even coverage on the lip. The thixotropic character of the glaze enables the quick drying (since no CMC is needed). The plate is finished by a follow-up bottom-dip, using a suction cup holder. Finally, the lip is finished using a brush with the same glaze slurry. Watch this on Instagram using the link below.

Context: Glazing bone bisque-firing plates.., HomeVSS tableware factory in..

Wednesday 12th August 2026

How much Zircon does it take to make a glaze crawl?

For G2934 cone 6 matte glaze: As little as 5%

G2934 matte glaze is crawling

The Zircon needed to opacify glazes has a side effect: Crawling. Even low percentages can induce this issue when other factors interplay (as is the case here). It often happens at sharp concaves (e.g. inside bottom corners on mugs). But here it is on surfaces disturbed during formation of the spout. This G2934 recipe has good melt fluidity, so that is not the issue. The issue appears related to adherence of the initial laydown. Here are some questions to consider:

  • Did the glaze crack on drying? Using some calcined kaolin, as specified in the recipe, helps reduce drying shrinkage.
  • Is it applied too thick? If mixed as a thixotropic slurry (1.44 specific gravity, and gelled) it should go on evenly but thinner. And stick better.
  • These areas that were disturbed during spout forming may require special attention to make sure the glaze adheres well (this is a Plainsman body, soluble salts that migrate to the surface during drying are affected by handling in the plastic and leather-hard states). Mix up some as a brushing glaze and apply a thin layer onto the bisque in the areas likely to crawl (the gum will ensure better adherence). Then dip the whole piece in the dipping glaze version.
  • An 80:20 blend of G2934 and G2926B glossy will be less likely to crawl. The mix can be adjusted to enable tuning matteness to a drop-and-hold firing schedule.
  • Use tin oxide as the opacifier instead of zircopax or superpax.
  • Mix the batch as a base coat dipping glaze, then it will adhere better to the bisque.
  • Reduce the amount of calcined kaolin (in the recommended recipe) in favor of raw kaolin (perhaps 5%) - that may produce a slurry with better coverage and adherence.

Context: Crawling in G2934Y Zircopax.., G2934 Cone 6 Matte.., An ordinary white mug.., Crawling

Wednesday 12th August 2026

Online Glaze Recipe Rescue:

Seeks good home for a magnesia blue

This "Minty Matte" glaze was found wandering in a Facebook group. With its excessive nepheline syenite coupled with very low SiO2 (thus high COE) it crazes on most clay bodies used by the potter who contacted me. Its tag traced it to Glazy 20196. I sometimes think of these as "shelter recipes", needing a "glaze rescue" after being caged and misunderstood online for years. This one could be deserving of a new home if given a little love! The love it needs is a simple understanding of the mechanism: It is just rutile saturation in a magnesia matte with a little cobalt to kick the blue. Recipes aren't carved in stone, the chemistry of this one can be altered to drop the COE a lot (by switching Na2O for MgO). I know that because G2934 magnesia matte also works with this mechanism. Transplanting it into that base would surely reduce crazing (with its 5.8 COE).

However, this recipe needs another rescue. From a misunderstanding. Although the potter contacting me was happy with the G2934 as a base for the rutile and cobalt, she had learned that durable glazes should have an R2O vs RO Ratio of around 0.3:0.7 (G2934 is 0.1:0.9). However, the R2O:RO ratio thing is misunderstood. Durability is much more about producing a well-melted homogeneous glass (but not over-fluid) with minimal phase separation and surface crystallization, good body fit and absence of large amounts of easily dissolved colorants.

Context: Titanium Dioxide in a.., 5 titanium dioxide in..

Wednesday 12th August 2026

The green underglaze bond is failing on impact

This is a fritted stoneware fired to cone 03. There is plenty of glass development to form a strong interface with glazes and underglazes. But this green commercial underglaze is not bonding well with the body. Repeated blows to the surface by a hammer (insufficient to break the piece but enough to test the glaze) are chipping off chunks of glaze/underglaze at the latter's interface with the body. This does happen with most other underglazes tested. The green underglaze is obviously more refractory and should be reformulated so that its stain medium develops enough fired maturity to counteract the refractory stain.

Context: Body glaze Interface

Tuesday 11th August 2026

Lithium and Spodumene prices are off-the-charts.

Can the percentage be reduced and still work?

The crystals that form as this cone 6 fluid-melt glaze solidifies are one of the minerals in the recipe: Spodumene. Actually β-spodumene. But it is so expensive, and there is 42% here! What would it take to reduce the cost of making this glaze ($52/kg in 2026)? Another flux could certainly make it just as melt-fluid, but would not grow spodumene crystals.

β-spodumene is Li2O - Al2O3 - 4SiO2 So the 0.22 Li2O in this glaze would require 0.22 Al2O3 and 0.88 SiO2 to crystallize as a β-spodumene-type lithium aluminosilicate. The glaze contains 0.24 Al2O3 and 1.41 SiO2. There is almost exactly enough lithium to combine with nearly all of the alumina as β-spodumene. The 2% rutile supplies TiO2; it acts as a nucleating agent. Replacing Li2O with another flux could maintain the melt fluidity, but Na2O, K2O or B2O3 cannot simply take the place of Li2O in β-spodumene.

It is possible that less spodumene could still do this. That could be tested by reducing Li2O to 0.1 and increasing Na2O to 0.23 (while maintaining the other oxides as-is). B2O3 could also be tried (it has a far lower thermal expansion). Of course, effecting changes in specific oxides requires some glaze chemistry (e.g. in an Insight-live.com account).

Context: Li2O from Spodumene instead.., LOI-gassing and expensive Spodumene..

Tuesday 11th August 2026

This underglaze is too thin to cover well.

I fixed it in under a minute. Sort of.

Gelled underglaze

Right: My attempts to apply a layer of watery white underglaze to leather-hard clay. Not surprising that I measured the water content of this at 68%. Yikes!

Left: After adding about a gram of Epsom Salts (and blender-mixing it in to dissolve), the slurry became thixotropic and gelled enough to enable applying a thicker layer with no problem. Note how it stays on the spoon. However, there is still an issue: Multple layers are needed, with lots of drying time between them. The low solids loading of this product also makes it tricky to use on bisque ware (more time is needed between the thinner coats it creates). Allowing it to settle and pouring off water, or evaporating some of the water to raise the specific gravity, would make it even better.

Context: A reason for DIY.., This underglaze went on..

Monday 10th August 2026

This underglaze went on too thin:

It’s specific gravity is too low

Terra cotta underglaze problem

Amaco V-303 Terra Cotta underglaze was applied in one coat at the leather-hard stage (on these Plainsman Snow mugs). It appeared to be thick enough on application and after bisque (left), but the clear overglaze on the right has diffused into it to melt it enough to lose its opacity. A higher specific gravity (lower water content) would make it possible to apply it thickly enough in one coat; this is especially important because each layer rewets the piece and adds a lengthy drying period. An appropriate specific gravity is thus the difference beween practical and impractical. Acheiving a better terra cotta texture and color is a prime candidate for DIY underglaze.

Context: Specific gravities on three.., Very low specific gravities.., This underglaze is too.., Specific gravity, Terra Cotta, Underglaze

Sunday 9th August 2026

Here’s why engobes shouldn’t melt

And also why they needn't contain zircon

An over mature engobe is not opaque

Since white burning slips are made from refractory materials they are not nearly as vitreous as terracotta bodies, they need help to mature and a frit is the natural answer. With the right amount, fired shrinkage can be matched to the body while the slip remains opaque.

L3685A slip on the left: An adjustment to the popular "Fish Sauce" recipe (which is basically a super plastic white body). 8% Frit 3110 replaces 8% Pyrax to make it glass-bond to the body better while remaining completely opaque.

Right L3685C: It has 15% frit, moving it into glaze territory, with translucency replacing opacity. Although expensive zircon could be added to restore opacity, that doesn’t fix the excessive firing shrinkage it now has, mismatching it with the body (which becomes more eventful the thicker it is applied).

Context: L3685U, Creating a Non-Glaze Ceramic.., Color matching restoration project.., White engobe flaking off.., A reason for DIY.., Applying an engobe by.., Potters can learn from.., Bi-Clay strips test compatibility.., Opacity, Engobe

Friday 7th August 2026



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